Phosphazenes are molecules containing a skeleton of alternating phosphorus and nitrogen atoms.  They can be joined together to make long chains or rings called polymers, some containing thousands of repeating segments linked end-to-end.  The polymer backbone can be designed according to the physical requirements of the application.  For example, linear high-molecular weight chains, block copolymers, organic-inorganic hybrid polymers, star, micelle and numerous other architectures are used for non-linear optics, controlled-drug delivery, biostability, bioerosion, high-performance elastomers and electronically conductive polymers have been synthesized at a major research university. Some examples are illustrated below.





Most commercially available polymers contain an organic carbon-based backbone.  Polyphosphazenes differ in that the backbone is inorganic, giving specific properties not available in carbon-based materials. 

The technology revolves around the principle that the chlorine atoms in polydichloro phosphazenes can be replaced by organic units that supplement the properties provided by the backbone.  For example, fluorinated side groups impart high solvent resistance, various carboxy-acid terminal groups bring biological utility, etc.  Polyphosphazenes have been synthesized with biological utility, optical behavior, selective permeability, ion and proton conductivity and various other physical and chemical characteristics.

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